(E)-1-(6-Chloro-2-methyl-4-phenyl-3-quinolyl)-3-(4-ethoxyphenyl)prop-2-en-1-one
نویسندگان
چکیده
In the title compound, C(27)H(22)ClNO(2), the phenyl substituent on the quinoline ring system is almost perpendicular to it [dihedral angle = 88.2 (1)°]. The quinoline ring system and the ethoxy-phenyl ring are oriented at dihedral angles of 79.5 (1) and 17.6 (3)°, respectively, with respect to the almost planar [r.m.s. deviation= 0.037 (3) Å] -C(=O)-C=C- linkage. In the crystal, the inversion-related mol-ecules exist as C-H⋯O hydrogen-bonded R(2) (2)(8) dimers.
منابع مشابه
(E)-1-(6-Chloro-2-methyl-4-phenyl-3-quinolyl)-3-(2-methoxyphenyl)prop-2-en-1-one
In the title compound, C(26)H(20)ClNO(2), the quinoline ring system and the methoxy-phenyl ring form dihedral angles of 69.97 (6) and 22.10 (10)°, respectively, with the propenone linkage. The 4-phenyl ring substituent on the quinoline ring system is oriented at a dihedral angle of 66.47 (3)°. In the crystal, mol-ecules exist as C-H⋯O hydrogen-bonded dimers. The structure is further stabilized ...
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In the title solvate, C29H21ClN2O2·C3H6O, a prop-2-en-1-one bridge links two quinolinyl residues; the latter are almost perpendicular [dihedral angle = 78.27 (6)°]. The dihedral angle between the quinonyl ring system and its pendant phenyl group is 59.78 (8)°. A small twist in the bridging prop-2-en-1-one group is noted [O=C-C=C torsion angle = -10.6 (3)°]. In the crystal, a three-dimensional a...
متن کامل(2E)-3-(4-Bromophenyl)-1-(2-methyl-4-phenyl-3-quinolyl)prop-2-en-1-one
The conformation about the ethene bond [1.316 (3) Å] in the title compound, C(25)H(18)BrNO, is E. The quinoline ring forms dihedral angles of 67.21 (10) and 71.68 (10)° with the benzene and bromo-substituted benzene rings, respectively. Highlighting the non-planar arrangement of aromatic rings, the dihedral angle formed between the benzene rings is 58.57 (12)°.
متن کامل1-(4-Bromophenyl)-3-(4-ethoxyphenyl)prop-2-en-1-one
The title compound, C(17)H(15)BrO(2), consists of two substituted benzene rings connected by a prop-2-en-1-one group. The mol-ecule is nearly planar and adopts an E configuration. The dihedral angle between the two benzene rings is 8.51 (19)°. The enone plane makes dihedral angles of 11.06 (19) and 7.69 (19)°, respectively, with the bromo-phenyl and ethoxy-phenyl rings. The mol-ecules are linke...
متن کامل(2E)-3-(2-Chloro-6-methyl-3-quinolyl)-1-(1-naphthyl)prop-2-en-1-one
In the title mol-ecule, C(23)H(16)ClNO, the quinoline and naphthalene ring systems are individually planar, with maximum deviations of 0.020 (2) and 0.033 (2) Å, respectively, and are inclined at a dihedral angle of 30.01 (4)°. Intra-molecular C-H⋯O and C-H⋯Cl inter-actions occur. The crystal structure is devoid of any classical hydrogen bonds, but symmetry-related mol-ecules are linked via wea...
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